4-(1H-2,3-Dihydronaphtho[1,8-de][1,3,2]diazaborinin-2-yl)-1-ethylpyridin-1-ium iodide

Author:

Hashimoto Shu,Okuno Tsunehisa

Abstract

The title compound, C17H17BN3I, is a type of diazaborinane featuring substitution at the 1, 2, and 3 positions of the nitrogen–boron six-membered heterocycle. The organic molecule has a planar structure, the dihedral angle between the pyridyl ring and the fused ring system being 3.46 (4)°. In the crystal, molecules are stacked in a head-to-tail manner. The iodide ion makes close contacts with three organic molecules and supports the alternating stack.

Funder

Wakayama University

Publisher

International Union of Crystallography (IUCr)

Reference8 articles.

1. 2-(4-Chlorophenyl)naphtho[1,8-de][1,3,2]diazaborinane

2. OLEX2: a complete structure solution, refinement and analysis program

3. Hashimoto, S., Miki, S. & Okuno, T. (2024). IUCrData, 9, x240369.

4. MIDA‐ and TIDA‐Boronates Stabilize α‐Radicals Through B−N Hyperconjugation

5. Rigaku OD (2020). CrysAlis PRO. Rigaku Corporation, Tokyo, Japan.

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