Author:
Jagan R.,Sathya D.,Sivakumar K.
Abstract
In the salt 1-methylpiperazine-1,4-diium bis(dihydrogen phosphate), C5H13N22+·2H2PO4−, (I), and the solvated salt 2-(pyridin-2-yl)pyridinium dihydrogen phosphate–orthophosphoric acid (1/1), C10H9N2+·H2PO4−·H3PO4, (II), the formation of O—H...O and N—H...O hydrogen bonds between the dihydrogen phosphate (H2PO4−) anions and the cations constructs a three- and two-dimensional anionic–cationic network, respectively. In (I), the self-assembly of H2PO4−anions forms a two-dimensional pseudo-honeycomb-like supramolecular architecture along the (010) plane. 1-Methylpiperazine-1,4-diium cations are trapped between the (010) anionic layers through three N—H...O hydrogen bonds. In solvated salt (II), the self-assembly of H2PO4−anions forms a two-dimensional supramolecular architecture with open channels projecting along the [001] direction. The 2-(pyridin-2-yl)pyridinium cations are trapped between the open channels by N—H...O and C—H...O hydrogen bonds. From a study of previously reported structures, dihydrogen phosphate anions show a supramolecular flexibility depending on the nature of the cations. The dihydrogen phosphate anion may be suitable for the design of the host lattice for host–guest supramolecular systems.
Publisher
International Union of Crystallography (IUCr)
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics
Cited by
8 articles.
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