Author:
Wu Ji-Pei,Cheng Yi-Chuan,Lu Lei,Wang Jun,Qiao Shan-Bao
Abstract
A novel three-dimensional CdII coordination framework, namely, poly[{μ-bis[4-(2-methylimidazol-1-yl)phenyl] ether-κ2
N
3:N
3′}(μ-naphthalene-1,4-dicarboxylato-κ3
O
1:O
4,O
4′)cadmium(II)], [Cd(C12H6O4)(C20H18N4O)]
n
or [Cd(1,4-NDC)(BMIOPE)]
n
, where 1,4-H2NDC is naphthalene-1,4-dicarboxylic acid and BMIOPE is bis[4-(2-methylimidazol-1-yl)phenyl] ether, has been prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetric analysis. The compound displays a novel fourfold interpenetrating diamond-like network. In addition, it not only shows a strong fluorescence emission in the solid state, but also exhibits excellent photocatalytic activity for the degradation of methylene blue (MB) at room temperature.
Publisher
International Union of Crystallography (IUCr)
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics
Reference33 articles.
1. Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate
2. Blatov, V. A. & Shevchenko, A. P. (2006). TOPOS. Version 4.0. Samara State University, Samara, Russia.
3. Brandenburg, K. & Putz, H. (2005). DIAMOND. Crystal Impact GbR, Bonn, Germany.
4. Bruker (2008). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
5. Bruker (2016). APEX3 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献