Author:
Butcher Ray J.,Gultneh Yilma,Yisgedu T. B.
Abstract
In the title complex, [Mn(C20H21N3)2](ClO4)2, two tridentate (2-methylbenzyl)bis(pyridin-2-ylmethyl)amine (L) ligands form the MnIIcomplex [MnL2](ClO4)2. The MnIIion lies on a twofold axis and the complex cation is significantly distorted from regular octahedral geometry. The packing is stabilized by weak C—H...O interactions between the cations and anions, which link them into a zigzag ribbon along [101]. The perchlorate anion is disordered and was constrained to be tetrahedral with two orientations having occupancies of 0.768 (4) and 0.232 (4). The 2-methylbenzyl moiety is also disordered over two sets of sites, with occupancies of 0.508 (15) and 0.492 (15).
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
1 articles.
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