Bis(diphenylmethylphosphine-κP)(disulfurdinitrido-κ2 N,S)platinum(II) dichloromethane solvate

Abstract

The title compound, [Pt(N2S2)(C13H13P)2]·CH2Cl2, contains PtII in a square-planar coordination. The five-membered PtS2N2 ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe2Ph analogue and one of the published PPh3 analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.