Author:
Kargar Hadi,Kia Reza,Ganji Fatemeh,Mirkhani Valiollah
Abstract
In the title Schiff base complex, [Cu(C19H18Cl2N2O2)], the CuIIion is coordinated in a distorted square-planar environment by two N atoms and two O atoms of the tetradentate ligand. The dihedral angle between the benzene rings is 36.86 (14)°. In the crystal, molecules are linked into inversion dimers by pairs of weak C—H...O hydrogen bonds. In addition, π–π [centroid–centroid distance = 3.7279 (16) Å] and weak C—H...π interactions are observed.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference9 articles.
1. Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds
2. Bruker (2005). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
3. {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate
4. Ligand environment and the structure of schiff base adducts and tetracoordinated metal-chelates
Cited by
2 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Synthesis, Experimental and Theoretical Studies on N,N′-Dipyridoxyl(4-Chloro-1,2-Phenylenediamine) Tetradentate Ligand and Its Copper(II) Complex;Journal of Structural Chemistry;2019-08
2. Di-μ2-acetato-1:2κ2O:O′;2:3κ2O:O′-bis{μ2-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ6O,N,N′,O′:O,O′;2:3κ6O,O′:O,N,N′,O′-tricopper(II);Acta Crystallographica Section E Structure Reports Online;2012-10-31