Di-μ-glutarato-κ4
O
1:O
5-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ2
N
2,N
3]copper(II)}
-
Published:2012-05-26
Issue:6
Volume:68
Page:m797-m797
-
ISSN:1600-5368
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Container-title:Acta Crystallographica Section E Structure Reports Online
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language:
-
Short-container-title:Acta Cryst E
Author:
Xu Wei,Feng Lan-Jing-Qian
Abstract
In the centrosymmetric dinuclear title complex, [Cu2(C5H6O4)2(C20H14N4)2(H2O)2], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water molecule is located at the apical position. Of the two water H atoms, one is engaged in an intramolecular O—H...O hydrogen bond, whereas the second is engaged in an intermolecular O—H...O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010].
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
1 articles.
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1. 1,2,4-Triazines and Their Benzo Derivatives;Comprehensive Heterocyclic Chemistry IV;2022