(Z)-N-[1-(Aziridin-1-yl)-2,2,2-trifluoroethylidene]-4-bromoaniline
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Published:2014-04-12
Issue:5
Volume:70
Page:o550-o550
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ISSN:1600-5368
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Container-title:Acta Crystallographica Section E Structure Reports Online
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language:
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Short-container-title:Acta Cryst E
Author:
Bunev Alexander S.,Vasiliev Maksim A.,Ostapenko Gennady I.,Peregudov Alexander S.,Khrustalev Victor N.
Abstract
The title compound, C10H8BrF3N2, crystallizes with two independent molecules in the asymmetric unit, which can be considered as being related by a pseudo-inversion center, so their conformations are different; the corresponding N=C—N—C torsion angles are 54.6 (5) and −50.5 (5)°. In the crystal, molecules related by translation in [001] interact through short intermolecular Br...F contacts [3.276 (2) and 3.284 (2) Å], thus forming two types of crystallographically independent chains.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference16 articles.
1. Mono-osmylation of dehydroamino acid dienes: synthesis of dehydroamino acids related to the azinomycins
2. Bruker (2001). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
3. Bruker (2003). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
4. Bruker (2005). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.
5. AnN-Substituted 6,7-Benzocoumarin-8,9-aziridine Derivative