Author:
Ismailova D. S.,Okmanov R. Ya.,Ziyaev A. A.,Shakhidoyatov Kh. M.,Tashkhodjaev B.
Abstract
The title compound, C16H20N4OS2, was synthesized by the reaction of 2-benzylsulfanyl-5-chloroacetamido-1,3,4-thiadiazole and piperidine in a 1:2 ratio. The planes of the acetamide and 1,3,4-thiadiazole units are twisted by 10.8 (4)°. The thiadiazole S atom and the acetamide O atom aresyn-oriented due to a hypervalent S...O interaction of 2.628 (4) Å. In the crystal, molecules form centrosymmetric dimersviaN—H...N hydrogen bonds. These dimers are further connected by C—H...O interactions into (100) layers.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
1 articles.
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1. 1,3,4-Thiadiazoles;Comprehensive Heterocyclic Chemistry IV;2022