Bis(N,N-dimethylethane-1,2-diamine)dithiocyanatocobalt(III) perchlorate: a redetermination
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Published:2006-03-15
Issue:4
Volume:62
Page:m776-m778
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ISSN:1600-5368
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Container-title:Acta Crystallographica Section E Structure Reports Online
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language:
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Short-container-title:Acta Cryst E
Author:
Sun Yu-Xi,Gu Ke-Qiang,Yang Guang,Xie Fei,Sun Yun-Jin
Abstract
The crystal structure of the title compound, [Co(NCS)2(C4H12N2)2]ClO4, has been reported previously by Eminger, Fallab, Zehnder & Dobler [Helv. Chim. Acta (1992), 75, 1245–1250], with an R value of 0.074. However, no coordinates are available. We present here a redetermination of this structure using new intensity data. The CoIII atom, lying on an inversion centre, is six-coordinate in an octahedral geometry. The perchlorate anion, located on a twofold axis, is disordered over two orientations.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry