Bis(diphenylphosphorothioyl) trisulfide

Author:

Kulcsar Monika,Silvestru Anca,Vonas Marius

Abstract

In the title compound, C24H20P2S5, the P atoms are arrangedtranswith respect to the S3group and the S=P—S—S systems havecisoidgeometry, with an average S—P—S—S torsion angle of −56.7°. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33 (12) and 75.67 (10)°. In the crystal structure, the molecules are linked into chains running parallel to theaaxis by weak intermolecular C—H...S hydrogen bonds. Centrosymmetrically related chains are further connected by π–π stacking interactions, with a centroid-to-centroid distance of 3.795 (5) Å.

Publisher

International Union of Crystallography (IUCr)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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