Author:
Shi Zhan-Wang,Qin Yan,Lin Yan-Xia,Wu Wei,Liang Peng
Abstract
In the title compound, [CoCl(C10H7N3S)2]Cl·2H2O, the CoIIatom is five-coordinated by four N atoms from two chelating 2-(1,3-thiazol-4-yl)-1H-benzimidazole ligands and one Cl atom in a distorted trigonal–bipyramidal geometry. In the crystal, N—H...O and O—H...Cl hydrogen bonds and π–π interactions between the thiazole, imidazole and benzene rings [centroid-to-centroid distances 3.546 (2), 3.683 (2) and 3.714 (2) Å] link the complex cations, chloride anions and uncoordinating water molecules into a three-dimensional network.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference14 articles.
1. Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.
2. Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
3. Synthesis, antimicrobial activity and chemotherapeutic potential of inorganic derivatives of 2-(4′-thiazolyl)benzimidazole{thiabendazole}: X-ray crystal structures of [Cu(TBZH)2Cl]Cl·H2O·EtOH and TBZH2NO3 (TBZH=thiabendazole)
4. Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4′-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands
5. 2-(1,3-Thiazol-4-yl)benzimidazolium nitrate monohydrate