Tris(cyclohexylammonium)cis-dichloridobis(oxalato-κ2O1,O2)stannate(IV) chloride monohydrate

Author:

Sarr Modou,Diallo Waly,Diasse-Sarr Aminata,Plasseraud Laurent,Cattey Hélène

Abstract

The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions incispositions coordinate octahedrally to the central SnIVatom. The cohesion of the molecular entities is ensured by the formation of N—H...O, O—H...O, O—H...Cl and N—H...Cl interactions involving cations, anions and the lattice water molecule, giving rise to a layer-like arrangement parallel to (010).

Publisher

International Union of Crystallography (IUCr)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Synthesis, structure determination and characterization by UV–Vis and IR spectroscopy of bis(diisopropylammonium) cis-dichloridobis(oxalato-κ2 O 1,O 2)stannate(IV);Acta Crystallographica Section E Crystallographic Communications;2019-05-03

2. Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2 O 1,O 2)stannate(IV);Acta Crystallographica Section E Crystallographic Communications;2018-03-09

3. Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV);Acta Crystallographica Section E Structure Reports Online;2014-05-17

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