[Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate
-
Published:2012-03-17
Issue:4
Volume:68
Page:m428-m428
-
ISSN:1600-5368
-
Container-title:Acta Crystallographica Section E Structure Reports Online
-
language:
-
Short-container-title:Acta Cryst E
Author:
Karakus Mehmet,Woollins J. Derek,Lönnecke Peter,Hey-Hawkins Evamarie
Abstract
The title compound, [Fe2Ti(C5H5)4)(C10H8O2P2S4)]·3C4H8O, contains a central seven-membered TiO2P2S2ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti—O distance being marginally longer for the anisyl derivative. Two tetrahydrofuran solvent molecules are each disordered on a twofold axis.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference7 articles.
1. Brandenburg, K. (2005). DIAMOND. Crystal Impact GbR, Bonn, Germany.
2. WinGXsuite for small-molecule single-crystal crystallography
3. On enantiomorph-polarity estimation
4. Oxford Diffraction (2009). CrysAlis PRO. Oxford Diffraction Ltd, Yarnton, England.
5. A short history ofSHELX