Author:
Zhao Qing-Lan,Li Guo-Peng
Abstract
In the title compound, [ZnBr2(C15H11N3)], the ZnIIion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on a twofold rotational axis that passes through the ZnIIion and the central ring of the terpy ligand. In the crystal structure, aromatic π–π interactions between terpy ligands [centroid–centroid distances = 3.6265 (9) Å] link molecules into stacks propagated in the [001] direction.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
5 articles.
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1. Structures of 1:1 Mononuclear Adducts of Zinc(II) Halides, ZnX2 (X=Cl, Br, I) and of New Hydrates of 1:1 Adducts of Zinc(II) Nitrate and Sulfate with Aromatic N,N′′-Bidentate Base Derivatives of Pyridine (bpy, phen);Australian Journal of Chemistry;2020
2. A Polyaromatic Terdentate Binding Unit with Fused 5,6-Membered Chelates for Complexing s-, p-, d-, and f-Block Cations;Inorganic Chemistry;2013-04-19
3. Urease inhibitory activities of ZnBr2 and ZnI2 complexes of terpyridine derivatives: Systematic investigation of aryl substituents on urease inhibitory activities;Polyhedron;2012-09
4. Protonation and Complexation Properties of Polyaromatic Terdentate Six-Membered Chelate Ligands;Inorganic Chemistry;2012-07-19
5. catena-Poly[[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ2O:O′];Acta Crystallographica Section E Structure Reports Online;2009-11-14