Abstract
The title compound, [Eu(C9H10BN6)(C19H15O2)2(C3H7NO)] or [TpEu(Anthracac)2(DMF)], was synthesized by reaction of a tris(pyrazolyl)borate (Tp−) Eu3+ complex with 3-(anthracen-9-yl)pentane-2,4-dione (HAnthracac) in the presence of triethylamine. In the title compound, Eu3+ is located in an octavertex square-pyramidal coordination environment. In the two Anthracac− ligands, the anthracene and nearly planar acetylacetonate fragments are almost orthogonal. Neighboring molecules of TpEu(Anthracac)2(DMF) are connected in the crystal by intermolecular van der Waals interactions, while π-stacking interactions are limited to the edges of two anthracene rings.
Funder
National Research Foundation of Ukraine
National Academy of Sciences of Ukraine
National Science Foundation, Directorate for Mathematical and Physical Sciences
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Foreword to the special virtual issue in tribute to Jerry P. Jasinski;Acta Crystallographica Section E Crystallographic Communications;2022-11-30