Crystal structure of bis{(Z)-(benzylamino)[(5Z)-2-(benzylimino-κN)-5-(2-methoxy-2-oxoethylidene)-4-oxothiolan-3-ylidene]methanethiolato-κS}copper(II)

Abstract

The title complex, [Cu(C22H19N2O3S2)2], was obtained from the reaction between (Z)-methyl 2-(5-benzylimino-4-benzylcarbamothioyl-3-oxothiolan-2-ylidene)acetate and Cu(NO3)2. The CuIIatom is tetracoordinated by twoN,S-bidentate ligands, forming a highly distorted tetrahedral environment. The structure displays two intramolecular N—H...O hydrogen bonds.