Author:
Ferrence Gregory M.,Kocher Joshua L.
Abstract
The title compound, C7H14N2Si, crystallizes in a tetragonal space group and exists as an N—H...N hydrogen-bonded tetramer, formed around the crystallographic fourfold rotoinversion axis. The molecular identity is clearly the 5-trimethylsilyl-3-methyl-1H-pyrazole tautomer and the structure is isomorphous with that of 5-tert-butyl-3-methyl-1H-pyrazole [Foces-Foces & Trofimenko (2001).Acta Cryst.E57, o32–o34].
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
2 articles.
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1. Pyrazoles;Comprehensive Heterocyclic Chemistry IV;2022
2. Organosilicon azoles: Structure, silylotropy and NMR spectroscopy;Advances in Heterocyclic Chemistry;2021