Author:
Honkeldieva Muhabbat T.,Talipov Samat A.,Kunafiev Rishad,Ibragimov Bakhtiyar T.
Abstract
The title compound, C44H44N2O8, (systematic name: 1,1′,6,6′-tetrahydroxy-5,5′-diisopropyl-8,8′-bis{[(4-methoxyphenyl)iminiumyl]methyl}-3,3′-dimethyl-2,2′-binaphthalene-7,7′-diolate) has been obtained by the addition ofp-anizidine to gossypol dissolved in dichloromethane. In the solid state, the title compound exists in the enamine or quinoid form. The two naphthyl moieties are inclined to one another by 72.08 (5)°. The pendant phenyl rings are inclined at 22.26 (14) and 23.86 (13)° to the corresponding naphthyl rings. In the crystal, molecules are incorporated into layers through inversion-related pairs of O—H...O interactions [graph setsR22(20) andR22(10)] and translation-related O—H...O interactions [graph setC(15)]. The packing of these layers in the crystal structure gives rise to channels in the [011] direction, with hydrophobic interactions occurring between adjacent layers. The channels are 5–7 Å wide, and the void volume of each cell is 655 Å3, corresponding to 26.6% of the cell volume. Disordered guest molecules, probably solvent and water molecules, occupy these voids of the crystal; their contribution to the scattering was removed with the SQUEEZE routine [Spek (2015).Acta Cryst. C71, 9–18] ofPLATON[Spek (2009).Acta Cryst.D65, 148–155].
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference20 articles.
1. Gossypol, a Pigment of Cottonseed.
2. X-ray structural investigation of gossypol and its derivatives XXIV. Structure of a clathrate of dianilinegossypol with 1,2-dichloroethane
3. Gossypol: a contraceptive for men
4. OLEX2: a complete structure solution, refinement and analysis program
5. Gdaniec, M., Ibragimov, B. T. & Talipov, S. A. (1996). Gossypol, in Comprehensive Supramolecular Chemistry, edited by D. D. MacNicol, F. Toda & R. Bishop, Vol. 6, Solid-state Supramolecular Chemistry: Crystal Engineering, pp. 117-145. Oxford: Pergamon Press.
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献