Bis[1,2-bis(4-tert-butylphenyl)ethylene-1,2-dithiolato(1−)]nickel(II) pentane 0.25-solvate
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Published:2023-02-17
Issue:3
Volume:79
Page:182-186
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ISSN:2056-9890
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Container-title:Acta Crystallographica Section E Crystallographic Communications
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language:
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Short-container-title:Acta Cryst E
Author:
Das Gupta Titir,
Applebaum Jack,
Broussard William,
Mack Carson,
Wu Che,
Mague Joel T.,
Donahue James P.ORCID
Abstract
The title compound, [Ni(C22H26S2)2], 1, is a square-planar D
2h
-symmetric compound that occurs on a general position in non-centrosymmetric tetragonal P41212 (No. 92) with ¼ eq of n-pentane (C5H12) as co-crystallite. Intraligand bond lengths show the dithiolene ligands to be in their half-oxidized radical monoanionic form. Intermolecular
t
Bu-C—H...arenecentroid and
t
Bu-C—H...NiS2C2 centroid close contacts guide the packing arrangement for 1.
Funder
National Science Foundation, Directorate for Mathematical and Physical Sciences
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry