Abstract
A three-dimensional coordination polymer, poly[hexaaqua(μ4-glutarato)bis(μ3-sulfato)dineodymium(III)], [Nd2(glutarato)(SO4)2(H2O)6]
n
(glutarato2– = C5H6O4
2–), 1, consisting of cationic {Nd2(H2O)6(SO4)2}
n
2n+ layers linked by bridging glutarate ligands, was synthesized by the microwave-heating technique within few minutes. The crystal structure of 1 consists of two crystallographically independent TPRS-{NdIIIO9} (TPRS is tricapped trigonal–prismatic geometry) units that form an edge-sharing dinuclear cluster interconnected to neighbouring dimers by the μ3-SO4
2– anions, yielding a cationic two-dimensional {Nd2(H2O)6(SO4)2}
n
2n+ sheet. Adjacent cationic layers are then linked via the μ4-glutarato2– ligands into a three-dimensional coordination network. Strong O—H...O hydrogen bonds are the predominant interaction in the crystal structure.
Funder
Faculty of Science, Chiang Mai University
Development and Promotion of Science and Technology Talent Project (DPST) through a research fund for graduates with first placement
CMU Junior Research Fellowship Program
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
1 articles.
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