Crystal structure of 2-(3-nitrophenyl)-1,3-dithiane
-
Published:2015-02-13
Issue:3
Volume:71
Page:o181-o182
-
ISSN:2056-9890
-
Container-title:Acta Crystallographica Section E Crystallographic Communications
-
language:
-
Short-container-title:Acta Cryst E
Author:
Caracelli Ignez,Zukerman-Schpector Julio,Stefani Hélio A.,Gozhina Olga,Tiekink Edward R. T.
Abstract
In the title compound, C10H11NO2S2, the 1,3-dithiane ring has a chair conformation with the 1,4-disposed C atoms being above and below the remaining four atoms. The nitrobenzene substituent occupies an equatorial position and forms a dihedral angle of 88.28 (5)° with the least-squares plane through the 1,3-dithiane ring. The nitro group is twisted out of the plane of the benzene ring to which it is connected, forming a dihedral angle of 10.12 (3)°. In the crystal, molecules aggregate into supramolecular zigzag chains (glide symmetry along thecaxis)vianitro–benzene N—O...π [N—O...Cg(benzene) = 3.4279 (18) Å and angle at O = 93.95 (11)°] interactions. The chains pack with no specific intermolecular interactions between them.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference11 articles.
1. Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.
2. Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
3. Crystal structure determination and refinementviaSIR2014
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献