Crystal structure of dimethyl-1κ2C-bis(μ-4-methylphenolato-1:2κ2O:O)(N,N,N′,N′-tetramethylethylenediamine-2κ2N,N′)indium(III)lithium(I)

Author:

Briand Glen G.,Decken Andreas,Hoey Marshall R.

Abstract

The mixed bimetallic title compound, [InLi(CH3)2(C7H7O)2(C6H16N2)] or [(tmeda)Li-μ-(4-MeC6H4O)2InMe2] (tmeda isN,N,N′,N′-tetramethylethylenediamine), exhibits a four-membered LiO2In ring coreviabridging 4-methylphenolate groups. The Li and In atoms are in distorted tetrahedral N2O2and C2O2bonding environments, respectively. The Li atom is further chelated by a tmeda group, yielding a spirocyclic structure.

Publisher

International Union of Crystallography (IUCr)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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