trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC 1)tin(IV): crystal structure and Hirshfeld surface analysis

Author:

Amin Nur Adibah Binti Mohd,Hussen Rusnah Syahila Duali,Lee See Mun,Halcovitch Nathan R.,Jotani Mukesh M.,Tiekink Edward R. T.ORCID

Abstract

The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C—H...F, C—H...Cl and C—H...π interactions, giving rise to a three-dimensional network. The respective influences of the Cl...H/H...Cl and F...H/H...F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface.

Funder

Sunway University

University of Malaya

Ministry of Higher Education, Malaysia (MOHE) Fundamental Research Grant Scheme

Publisher

International Union of Crystallography (IUCr)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Cited by 9 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Non-covalent bonded 1D-3D supramolecular salts from tert‑butylamine and organic acids;Journal of Molecular Structure;2022-04

2. Crystal structure of dichlorido-bis(dimethyl sulfoxide-κO)bis(4-methylphenyl-κC 1)tin(IV), C18H26Cl2O2S2Sn;Zeitschrift für Kristallographie - New Crystal Structures;2021-09-08

3. Crystal structure of dichloridodimethylbis(tri-4-tolylphosphane oxide-κO)-tin(IV), C44H48Cl2O2P2Sn;Zeitschrift für Kristallographie - New Crystal Structures;2020-10-27

4. Crystal structure of dichlorido-bis(dimethyl sulphoxide-κO)-bis(4-methylbenzyl-κC1)tin(IV), C20H30Cl2O2S2Sn;Zeitschrift für Kristallographie - New Crystal Structures;2020-08-26

5. Crystal structure of iodido-triphenyl-(triphenylphosphine oxide)tin(IV), C36H30IOPSn;Zeitschrift für Kristallographie - New Crystal Structures;2019-12-18

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