Author:
Zhang Yong,Qin Hongni,Wu Bing
Abstract
An NiII coordination polymer, namely, poly[(μ2-adamantane-1,3-dicarboxylato-κ4
O
1,O
1′:O
3,O
3′)[μ2-1,4-bis(2-methyl-imidazol-1-ylmethyl)benzene-κ2
N
3:N
3′]nickel(II)], [Ni(C12H14O4)(C16H18N4)]
n
or [Ni(adc)(bmib)]
n
, (I) [adc = adamantane-1,3-dicarboxylate, C12H14O4
2– and bmib = 1,4-bis(2-methyl-imidazol-1-ylmethyl)benzene, C16H18N4] was synthesized and characterized. It exhibits a one-dimensional extended structure built up from alternating [Ni2(bmib)2] 26-membered rings and [Ni2(adc)2] 16-membered rings. The nickel atom lies on a crystallographic twofold axis and both ligands are completed by mirror symmetry. The solid-state luminescence spectra of (I) and the bmib ligand show strong emissions at 442 and 410 nm, respectively.
Funder
Suzhou Industrial Park Institute of Services Outsourcing
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry