Crystal structure ofN-(2-{[2,6-bis(2,2,2-trifluoroacetamido)phenyl]disulfanyl}-3-(2,2,2-trifluoroacetamido)phenyl)-2,2,2-trifluoroacetamide
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Published:2015-08-06
Issue:9
Volume:71
Page:o639-o640
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ISSN:2056-9890
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Container-title:Acta Crystallographica Section E Crystallographic Communications
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language:
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Short-container-title:Acta Cryst E
Author:
Awasabisah Dennis,Powell Douglas R.,Richter-Addo George B.
Abstract
The title compound, C20H10F12N4O4S2, is an organic diaryl disulfide compound with trifluoroacetamide substituents at theortho-positions of each benzene ring. There are two molecules (labeledAandB) in the asymmetric unit. The F atoms of three of the –CF3groups exhibit rotational disorder over two positions each. The S—S bond distances are 2.0914 (7) and 2.0827 (6) Å for moleculesAandB, respectively. The dihedral angle between the S—S—C and S—C—C planes is 103.05 (15)° for moleculeAand 104.09 (15)° for moleculeB. The three-dimensional supramolecular architecture of the crystal is sustained by numerous N—H...O, N—H...S and C—H...O interactions.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
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