Author:
Safbri Siti Artikah M.,Halim Siti Nadiah Abdul,Jotani Mukesh M.,Tiekink Edward R. T.
Abstract
The title compound, [Cd(C6H12NOS2)2(C4H10N2)], features a distorted square-pyramidal coordination geometry about the central CdIIatom. The dithiocarbamate ligands are chelating, forming similar Cd—S bond lengths and define the approximate basal plane. One of the N atoms of the piperazine molecule, which adopts a chair conformation, occupies the apical site. In the crystal, supramolecular layers propagating in theacplane are formedviahydroxy-O—H...O(hydroxy), hydroxy-O—H...N(terminal-piperazine) and coordinated-piperazine-N—H...O(hydroxy) hydrogen bonds; the layers also feature methine-C—H...S interactions and S...S [3.3714 (10) Å] short contacts. The layers stack along theb-axis direction with very weak terminal-piperazine-N—H...O(hydroxy) interactions between them. An evaluation of the Hirshfeld surfaces confirms the importance of intermolecular interactions involving oxygen and sulfur atoms.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
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