Abstract
The title one-dimensional copper(II) coordination polymer, {[Cu(SO4)(C10H10N2)3]·C3H7NO·H2O}
n
or {[Cu(bzi)3(μ-O2SO2)]·H2O·DMF}
n
(bzi = 1-benzylimidazole, C10H10N2; DMF = N,N-dimethylformamide, C3H7NO), is constructed by monodentate bzi ligands and bridging sulfate anions, leading to chains propagating parallel to the c axis. Within a chain, there are two crystallographic independent CuII ions, each with site symmetry \overline{1}, which form [CuN2O2] and [CuN4O2] polyhedra alternating along the chain direction. The crystal structure is consolidated by weak hydrogen-bonding, C—H...π and π–π interactions, leading to the formation of a three-dimensional supramolecular network.
Funder
Department of Chemistry, Faculty of Science and Technology, Thammasat University, Thailand
the TINT to University Project of Thailand Institute of Nuclear Technology
the Thammasat University Research unit in Multifunctional Crystalline Materials and Applications Research Unit
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry