Abstract
The title compound, [Sn(CH3)2(C5H8NOS2)2], has the SnIVatom bound by two methyl groups which lie over the weaker Sn—S bonds formed by two asymmetrically chelating dithiocarbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the molecular packing are secondary Sn...S interactions [Sn...S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architectureviamethylene-C—H...S and methyl-C—H...O(morpholino) interactions. The Sn...S interactions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other intermolecular contacts.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
6 articles.
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