Abstract
The iron molybdate NaMgFe(MoO4)3{sodium magnesium iron(III) tris[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe2(MoO4)3and crystallizes in the triclinic space groupP-1. Its structure is built up from [Mg,Fe]2O10units of edge-sharing [Mg,Fe]O6octahedra which are linked to each other through the common corners of [MoO4] tetrahedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [101] direction in which the Na+cations are located.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
8 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Hydrothermal fabrication of novel nanocomposites Mx‐MoO3‐α‐NaFe2(MoO4)3‐α‐FeMoO4 (M = Al, Co, Ni, and Er) for highly efficient catalytic synthesis of 5‐aryl‐1H‐tetrazole analogs;Applied Organometallic Chemistry;2023-04-06
2. Structural and Spectroscopic Effects of Li+ Substitution for Na+ in LixNa1−xCaLa0.5Er0.05Yb0.45(MoO4)3 Upconversion Scheelite-Type Phosphors;Crystals;2023-02-20
3. Structural, Spectroscopic, Electric and Magnetic Properties of New Trigonal K5FeHf(MoO4)6 Orthomolybdate;Molecules;2023-02-08
4. Electronic structure, sodium diffusion and redox potentials of
low‐symmetry Na
M
Fe
(
MoO
4
)
3
(
M
= Mg, Ni);Journal of Computational Chemistry;2022-04-25
5. Ab Initio Study of NaMFe(MoO4)3 (M = Mn, Fe, Co, Ni, Zn): Electron Structure, Sodium Diffusion and Potentials;Physics of the Solid State;2022-04