Author:
Mathivathanan Logesh,Cruz Raquel,Raptis Raphael G.
Abstract
The trinuclear triangular cuprate anion of the title compound, tris[bis(triphenylphosphoranylidene)ammonium] tris(μ2-4-chloropyrazolato-κ2N:N′)-μ3-oxido-tris[(nitrato-κ2O,O′)cuprate(II)] nitrate monohydrate, (C36H30P2N)[Cu3(C3H2ClN2)3(NO3)3O]NO3·H2O, has point group symmetry 3., with the μ3-O atom located on the threefold rotation axis. The distorted square-pyramidal coordination sphere of the CuIIatom is completed by two N atoms oftrans-bridging pyrazolate groups and a chelating nitrate anion. The complex anion is slightly bent, with the nitrate and pyrazolate groups occupying positions above and below the Cu3plane, respectively. In the crystal, weak O—H...O and C—H...O hydrogen bonds, as well as π–π interactions, are present.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
3 articles.
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