Author:
Sangeetha Ramalingam,Balasubramani Kasthuri,Thanigaimani Kaliyaperumal,Jose Kavitha Savaridasson
Abstract
The asymmetric unit of the title molecular salt, C4H8N5
+·C2Cl3O2
−·H2O, coomprises a 2,4-diamino-6-methyl-1,3,5-triazin-1-ium cation, a trichloroacetate anion and a water molecule of solvation. The protonated N atom of the cation forms a hydrogen bond with a carboxyl O atom of the anion, which also acts as a hydrogen-atom acceptor with the water molecule. The cations form centrosymmetric dimeric units through R
2
2(8) N—H...N bond pairs and are extended into zigzag chains along the c-axis direction, also through similar cyclic R
2
2(8) dual N—H...N hydrogen-bonding interactions. The water molecule acts as a dual acceptor forming N—H...O hydrogen bonds between the amine groups of the cations, forming cyclic R
2
3(8) motifs. The second H atom of the water molecule also acts as a donor in an O—H...O hydrogen bond with the second carboxyl O atom, linking the chains along the b-axis direction. These interactions give rise to an overall three-dimensional supramolecular structure. A Hirshfeld surface analysis was employed in order to study the intermolecular interactions.
Funder
Department of Scientific and Industrial Research, Ministry of Science and Technology
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
6 articles.
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