Crystal structure of the η4-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2N,C1}(η5-pentamethylcyclopentadienyl)titanium(IV)
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Published:2018-01-01
Issue:1
Volume:74
Page:34-37
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ISSN:2056-9890
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Container-title:Acta Crystallographica Section E Crystallographic Communications
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language:
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Short-container-title:Acta Cryst E
Author:
Fischer Malte,Schmidtmann Marc,Beckhaus Rüdiger
Abstract
The molecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIVatom, comprising of one pentamethylcyclopentadienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one monodentate diphenylamide ligand. Except for van der Waals forces, there are no significant intermolecular interactions in the crystal.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference17 articles.
1. Brandenburg, K. & Putz, H. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.
2. Bruker (2015). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
3. Fischer, M., Schmidtmann, M. & Beckhaus, R. (2017). Organometallics, doi: 10.1021/acs. organomet. 7b00673.
4. Iron-Catalyzed Aromatic Amination for Nonsymmetrical Triarylamine Synthesis