Abstract
The crystal structure is reported of sodium 2-[2-(2,6-dichloroanilino)phenyl]acetate 3.5-hydrate or tetra-μ-aqua-κ8
O:O-decaaquabis{μ3-2-[2-(2,6-dichloroanilino)phenyl]acetato-κ3
O:O:O}tetrasodium(I) bis{2-[2-(2,6-dichloroanilino)phenyl]acetate}, {[Na4(C14H10Cl2NO2)2(H2O)14](C14H10Cl2NO2)2}
n
, which represents a new hydrate form of the NSAID sodium diclofenac (SD). The triclinic unit cell contains one ionic compound with formula Na4(C14H10Cl2NO2)4(H2O)14, in which two symmetry-related carboxylate anions C14H10Cl2NO2
− are bonded to a centrosymmetric [Na4]4+ core cationic cluster, while the others are only hydrogen bonded to the cationic cluster. The conformation for the anions is similar to that found in other diclofenac compounds, and the [Na4(Ocarbox)2(H2O)14]4+ cluster displays an unprecedented geometry, which can be described as an incomplete dicubane cluster formed by face-sharing incomplete cubes. A complex framework of O—H...O hydrogen bonds stabilizes the crystal structure. The herein reported crystal structure for SD·3.5H2O in space group P\overline{1} is different from those previously reported for other hydrates, namely SD·4.75H2O (P21) and SD·5H2O (P21/m).
Funder
Consejo Nacional de Ciencia y Tecnología
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
1 articles.
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