Author:
Moon Dohyun,Ryoo Keon Sang,Choi Jong-Ha
Abstract
The structure of the title compound, [Cr(NCS)2(cyclam)]2[ZnCl4] (cyclam = 1,4,8,11-tetraazacyclotetradecane, C10H24N4), has been determined from synchrotron data. The asymmetric unit contains two independent halves of the CrIIIcomplex cations and half of a tetrachloridozincate anion. In each complex cation, the CrIIIatom is coordinated by the four N atoms of the cyclam ligand in the equatorial plane and by two N-bound NCS−anions in atransaxial arrangement, displaying a distorted octahedral geometry with crystallographic inversion symmetry. The mean Cr—N(cyclam) and Cr—N(NCS) bond lengths are 2.065 (4) and 1.995 (6) Å, respectively. The macrocyclic cyclam moieties adopt centrosymmetrictrans-III configurations with six- and five-membered chelate rings in chair andgaucheconfigurations, respectively. The [ZnCl4]2−anion, which lies about a twofold rotation axis, has a slightly distorted tetrahedral geometry. The crystal packing is stabilized by hydrogen-bonding interactions between the N—H groups of the cyclam ligands, the S atoms of the NCS−groups and the Cl−ligands of the anion.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
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