Octane-1,8-diammonium dichloride monohydrate

Author:

Blerk Charmaine van,Kruger Gert J.

Abstract

The crystal structure of the title compound, C8H22N2 2+·2Cl·H2O, exhibits layered stacking in which the organic cations are separated by inorganic layers containing the chloride anions and the water molecules. The diammonium octane chain straddles a centre of inversion and the single water of crystallization sits on a twofold rotation axis. The diammonium octane chains pack in parallel layers with every second hydrocarbon layer alternating in a staggered configuration with respect to the previous layer. The three-dimensional hydrogen-bonding network links the organic and inorganic layers together in a highly intricate and complex manner. The torsion angles of the hydrocarbon chain deviate from 180° as a result of hydrogen-bonding interactions to the water molecule and the surrounding chloride anions.

Publisher

International Union of Crystallography (IUCr)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Crystal structure of octane-1,8-diaminium 4,4′-(diazene-1,2-diyl)dibenzoate monohydrate;Acta Crystallographica Section E Crystallographic Communications;2018-04-27

2. Salts of 4-aminobutyric acid and 6-aminohexanoic acid behaving as molecular Velcro;CrystEngComm;2017

3. Crystal structure, phase transition and conductivity study of two new organic – inorganic hybrids: [(CH2)7(NH3)2]X2, X = Cl/Br;Journal of Molecular Structure;2017-01

4. Pentane-1,5-diaminium dibromide;Acta Crystallographica Section C Crystal Structure Communications;2013-04-10

5. Self-assembling ensembles of silicomolybdic acid-diamines;Russian Journal of General Chemistry;2012-03

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