(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide

Abstract

The title compound, C15H14BrN3O2S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thioamide form. The two rings in the molecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, molecules are linked through pairs of N—H...O and O—H...S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intramolecular N—H...N, O—H...O and C—H...π interactions are also present.