Author:
Fabiani Claro Flores Alex,Correia Flores Darlene,Rosa de Menezes Vicenti Juliano,Pizzuti Lucas,Teixeira Campos Patrick
Abstract
In the crystal structure of the title compound, C14H12Cl3NO2, no classical hydrogen-bonding interactions are observed. The methylene fragments of the benzyl groups participate in non-classic hydrogen-bond interactions with the carbonyl O atoms of neighboring molecules, generating co-operative centrosymmetric dimers withR55(10) ring motifs. The overall molecular arrangement in the unit cell seems to be highly influenced by secondary non-covalent weak C—Cl...π [Cl...Cg(phenyl ring) = 3.732 (2) Å] and C—O...π [O...Cg(pyrrolidine ring) = 2.985 (2) Å] contacts.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference11 articles.
1. 1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
2. A Medicinal Chemist’s Guide to Molecular Interactions
3. 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide
4. Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.
5. Bruker (2009). APEX2, SAINT and XPREP. Bruker AXS Inc., Madison, Wisconsin, USA.
Cited by
4 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献