Author:
Lu Wen-Jie,Zhong Kai-Long,Zhu Yi-Min
Abstract
In the structure of the title compound, [Cd(SO4)(C12H8N2)2]·C2H6O2, the [Cd(SO4)(C12H8N2)2] and C2H6O2 entities are connected by hydrogen bonding. The formula unit lies on a special position of site symmetry 2. The CdII centre is coordinated by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from the bidentate sulfate ligand in a distorted octahedral geometry. The two chelating NCCN groups subtend a dihedral angle of 74.50 (9)°.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
13 articles.
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1. Synthesis, characterization, and luminescence of zinc(II) and cadmium(II) coordination complexes: [Zn(phen)$_{2}$(CH$_{3}$COO)](ClO$_{4})$, [Zn(bpy)$_{2}$(ClO$_{4})$](ClO$_{4})$, and [Cd(phen)$_{2}$(NO$_{3})_{2}$];TURKISH JOURNAL OF CHEMISTRY;2013
2. Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) butane-2,3-diol monosolvate;Acta Crystallographica Section E Structure Reports Online;2012-12-12
3. Diaquabis(1,10-phenanthroline-κ2N,N′)cadmium sulfate hexahydrate;Acta Crystallographica Section E Structure Reports Online;2011-10-29
4. Structural and spectroscopic parameters of distortion in [Cu(bpy)2(O2SO2)]·CH3OH and [Cu(bpy)3][SO4]·7.5H2O – Synthesis, crystal structure, spectroscopic and magnetic properties;Polyhedron;2011-05
5. Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)cobalt(II) butane-2,3-diol monosolvate;Acta Crystallographica Section E Structure Reports Online;2011-03-15