Author:
Ding Cai-Feng,Miao Yan-Fang,Tian Bing-Qing,Li Xue-Mei,Zhang Shu-Sheng
Abstract
In the title compound, [NiCl2(C14H12N2)(H2O)], there are two molecules in the asymmetric unit. Each Ni atom is five-coordinate in a geometry between trigonal–bipyramidal and tetragonal–pyrimidal. Molecules are linked into a three-dimensional framework by O—H...Cl and C—H...Cl hydrogen bonds. The packing is further stabilized by π–π interactions between the phenanthroline ring systems.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
5 articles.
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1. Neocuproine/nitrato complexes of Ni(II). Neutral and cationic species including salts with TCNQ: Preparation, chemical and spectroscopic properties and comparative structural chemistry;Journal of Molecular Structure;2024-01
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