Author:
Setifi Zouaoui,Setifi Fatima,El Ammari Lahcen,El-Ghozzi Malika,Sopková-de Oliveira Santos Jana,Merazig Hocine,Glidewell Christopher
Abstract
In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)]nor [Cu(tcnoet)Cl(phen)]n, where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetracyano-2-ethoxypropenide, the axially elongated (4 + 2) coordination polyhedron around the CuIIcentre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C—H...N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two –C(CN)2units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment.
Publisher
International Union of Crystallography (IUCr)
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics
Cited by
22 articles.
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