(H3O)2NaAl3F12, isostructural with A 2NaAl3F12 (A = K+, Rb+, Cs+) fluorides having HTB-type sheets-Reference-Cited by-同舟云学术

(H3O)2NaAl3F12, isostructural with A 2NaAl3F12 (A = K+, Rb+, Cs+) fluorides having HTB-type sheets

Published:2014-04-30 Issue:5 Volume:70 Page:512-516
ISSN:2053-2296
Container-title:Acta Crystallographica Section C Structural Chemistry
language:
Short-container-title:Acta Crystallogr C

Author:

Jouffret Laurent,Lhoste Jerome,Hemon-Ribaud Annie,Leblanc Marc,Maisonneuve Vincent

Abstract

The title compound, (H3O)2NaAl3F12 [dihydronium sodium trialuminum(III) dodecafluoride], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, sodium hydroxide, 1,2,4-triazole and aqueous HF in ethanol at 463 K for 48 h. The structure consists of AlF6 octahedra organized in [AlF4 −] n HTB-type sheets (HTB is hexagonal tungsten bronze) separated by H3O+ and Na+ cations.

Publisher

International Union of Crystallography (IUCr)

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics

Link

http://journals.iucr.org/c/issues/2014/05/00/eg3155/eg3155.pdf

Reference33 articles.

1. Adil, K., Cadiau, A., Hémon-Ribaud, A., Maisonneuve, V. & Leblanc, M. (2010). Functionalized Inorganic Fluorides: Synthesis, Characterizations & Properties of Nanostructured Solids, edited by A. Tressaud, pp. 347-381. New York: John Wiley & Sons Inc.

2. Novel Layered Hybrid Fluoroaluminate in the Composition Space Diagram of the Al(OH)3-HguaCl-HFaq-EtOH System

3. Brandenburg, K. (2012). DIAMOND. Crystal Impact GbR, Bonn, Germany.

4. Bruker (2013). APEX2 and SAINT-Plus. Bruker AXS Inc., Madison, Wisconsin, USA.

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1. ChemInform Abstract: (H3O)2NaAl3F12, Isostructural with A2NaAl3F12(A: K+, Rb+, Cs+) Fluorides Having HTB-Type Sheets.;ChemInform;2014-06-26