Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ2N3,S]nickel(II)-Reference-Cited by-同舟云学术

Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ2N3,S]nickel(II)

Published:2015-01-14 Issue:2 Volume:71 Page:m26-m27
ISSN:2056-9890
Container-title:Acta Crystallographica Section E Crystallographic Communications
language:
Short-container-title:Acta Cryst E

Author:

Howlader M. B. H.,Begum M. S.,Sheikh M. C.,Miyatake R.,Zangrando E.

Abstract

In the title complex, [Ni(C15H21N2S2)2], the NiIIatom exhibits a square-planar coordination geometry and is located on an inversion centre leading to atransconfiguration of theN,S-chelating ligands. In the crystal, the complex molecules stack at a distance of 4.6738 (3) Å along theaaxis, which exclude any significant interactions between the aromatic rings.

Publisher

International Union of Crystallography (IUCr)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://journals.iucr.org/e/issues/2015/02/00/ds2244/ds2244.pdf

Reference11 articles.

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2. Crystal structure ofS-hexyl (E)-3-(4-methylbenzylidene)dithiocarbazate

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4. Coordination chemistry of [methyl-3-(4-benzyloxyphenyl)methylene]dithiocarbazate with divalent metal ions: crystal structures of the N,S Schiff base and of its bis-chelated nickel(II) complex

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