Author:
Daszkiewicz Marek,Gulay Lubomir D.,Shemet Vasylyna Ya.
Abstract
The crystal structure of the R
2SnS5 (R = Pr, Nd, Gd and Tb) compounds has been investigated using X-ray single-crystal diffraction. Crystal architecture and structural relationships among U3S5, Y2HfS5, R
2SnS5 compounds are discussed and a structural origin is determined. It is shown that the complex architecture of the crystal structure of Eu5Sn3S12 is a result of interweaving of the simple crystal structures. The location of the copper ions in the non-stoichiometric compound Y2Cu0.20Sn0.95S5 is proposed on the basis of comparative analysis of the R—S interatomic distances in the R
2SnS5 series of compounds.
Publisher
International Union of Crystallography (IUCr)
Subject
General Biochemistry, Genetics and Molecular Biology,General Medicine
Cited by
16 articles.
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