Synthesis, structure, thermal and non-linear optical properties of L-argininium hydrogen selenite

Author:

de Matos Gomes E.,Nogueira E.,Fernandes I.,Belsley M.,Paixão J. A.,Matos Beja A.,Ramos Silva M.,Martín-Gil J.,Martín-Gil F.,Mano J. F.

Abstract

L-Argininium hydrogen selenite (C6H15N4O2HSeO3) is a new semiorganic compound of the hydrogen selenite family with non-linear optical properties. The crystal lattice is monoclinic with unit-cell parameters a = 22.493 (5), b = 5.1624 (13), c = 9.730 (4) Å, β = 95.68 (3)°, V = 1124.3 (6) Å3, Z = 4, space group C2. Second-harmonic generation measurements performed on powder samples, using a Q-switched Nd:Yag laser (λ = 1064 nm), showed the second-harmonic power to be about twice that of urea. Differential scanning calorimetry measurements revealed the existence of a phase transition with onset at 289 K.

Publisher

International Union of Crystallography (IUCr)

Subject

General Biochemistry, Genetics and Molecular Biology,General Medicine

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