Zirconium Oxide Stabilized By Scandium (III) And Cerium (IV) Complex Oxides As The Basis For Preparation Of Thick Films And Multilayers Structures For Low Temperature (600 °C) Fuel Cell-Reference-Cited by-同舟云学术

Zirconium Oxide Stabilized By Scandium (III) And Cerium (IV) Complex Oxides As The Basis For Preparation Of Thick Films And Multilayers Structures For Low Temperature (600 °C) Fuel Cell

Published:2018 Issue:1 Volume:6 Page:16-20
ISSN:2312-3222
Container-title:French-Ukrainian Journal of Chemistry
language:
Short-container-title:Fr. Ukr. J. Chem.

Author:

Vasylyev Oleksandr¹,Brodnikovskyi Yehor¹,V'yunov Oleg²,Kovalenko Leonid²,Yanchevskii Oleg²,Belous Anatolii²

Affiliation:

1. Institute for Problems of Materials Science, Ukrainian NAS

2. V.I. Vernadskii Institute of General & Inorganic Chemistry, Ukrainian NAS

Abstract

Weakly agglomerated zirconium dioxide nanopowders stabilized by complex oxides of scandium (III) and cerium (IV) were synthesized by precipitation from aqueous solutions. Using weakly agglomerated nanopowders, thick films were prepared by tape casting on a-Al2O3 substrates. These thick films have high oxygen conductivity; and their electron conductivity is lower than oxygen conductivity by 4 orders of magnitude. A multilayer system consisting of films of polycrystalline porous anode and solid electrolyte was prepared. The diffusion of cations in the anode boundary layer and change in the chemical composition of the electrolyte film are not observed at optimum synthesis conditions.

Publisher

Taras Shevchenko National University of Kyiv

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