Crystal structure of the Sr6Nb4ZrO18 slab perovskite-like compound-Reference-Cited by-同舟云学术

Crystal structure of the Sr6Nb4ZrO18 slab perovskite-like compound

Published:2015 Issue:2 Volume:3 Page:65-71
ISSN:2312-3222
Container-title:French-Ukrainian Journal of Chemistry
language:
Short-container-title:Fr. Ukr. J. Chem.

Author:

Titov Yuri¹,Belyavina Nadezhda¹,Slobodyanik Mykola¹,Polubinskii Vitaly¹,Nakonechna Olesya¹

Affiliation:

1. Taras Shevchenko National University of Kyiv

Abstract

The Sr6Nb4ZrO18 niobatozirconate has been synthesized from the Sr5Nb4O15 four-layer perovskite and the SrZrO3 perovskite at T = 1670 K by ceramic technique. Crystal structure of the Sr6Nb4ZrO18 compound has been studied by the X-ray powder diffraction method. It was shown that crystal structure of the Sr6Nb4ZrO18 (a = 0.5687(1) nm, c = 4.146(1) nm, R-3m space group) belongs to the Ba6Nb4TiO18-type with five-layer perovskite-like structure. The crystal structure features of the Sr6Nb4BIVO18 compounds (BIV = Ti, Sn, Zr) has been analyzed. The correlation between composition and crystal structure features for all Sr6Nb4BIVO18 (BIV = Ti, Sn, Zr) compounds, which leads to destruction slab perovskite-like structure has been revealed.

Publisher

Taras Shevchenko National University of Kyiv

Reference20 articles.

1. SEBASTIAN M. INTRODUCTION. Dielectric Materials for Wireless Communication Elsevier, Oxford: Elsevier; 2008. https://doi.org/10.1016/b978-0-08-045330-9.00001-7

2. Lichtenberg F, Herrnberger A, Wiedenmann K. Synthesis, structural, magnetic and transport properties of layered perovskite-related titanates, niobates and tantalates of the type AnBnO3n+2, A′Ak−1BkO3k+1 and AmBm−1O3m. Progress in Solid State Chemistry 2008;36(4):253-387. https://doi.org/10.1016/j.progsolidstchem.2008.10.001

3. Fang L, Zhang H, Huang T, Yuan R, Dronskowski R. Preparation, structure and dielectric properties of Ba4LaMNb3O15 (M = Ti, Sn ) ceramics. Materials Research Bulletin 2004;39(11):1649-1654. https://doi.org/10.1016/j.materresbull.2004.05.015

4. Rawal R, McQueen A, Gillie L, Hyatt N, McCabe E, Samara K, Alford N, Feteira A, Reaney I, Sinclair D. Influence of octahedral tilting on the microwave dielectric properties of A[sub 3]LaNb[sub 3]O[sub 12] hexagonal perovskites (A=Ba, Sr). Appl. Phys. Lett. 2009;94(19):192904. https://doi.org/10.1063/1.3129867

5. Kuang X, Allix M, Claridge J, Niu H, Rosseinsky M, Ibberson R, Iddles D. Crystal structure, microwave dielectric properties and AC conductivity of B-cation deficient hexagonal perovskites La5MxTi4–xO15 (x = 0.5, 1; M = Zn, Mg, Ga, Al). Journal of Materials Chemistry 2006;16(11):1038. https://doi.org/10.1039/b513696b