Ring-opening polymerization of ɛ-caprolactone with dilithium tetra-tert-butylzincate under mild conditions
Author:
Publisher
Springer Science and Business Media LLC
Subject
Materials Chemistry,Polymers and Plastics
Link
http://www.nature.com/articles/pj201476.pdf
Reference12 articles.
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2. Kitayama, T., Yamaguchi, H., Kanzawa, T. & Hirano, T. Living ring-opening polymerization of ɛ-caprolactone with combinations of tert-butyllithium and bilky aluminium phenoxides. Polym. Bull. 45, 97–104 (2000).
3. Kobayashi, M., Matsumoto, Y., Uchiyama, M. & Ohwada, T. A new chemoselective anionic polymerization method for poly(N-isopropylacrylamide) (PNIPAm) in aqueous media: design and application of bulky zincate possessing little basicity. Macromolecules 37, 4339–4341 (2004).
4. Uchiyama, M., Kobayashi, Y., Furuyama, T., Nakamura, S., Kajihara, Y., Miyoshi, T., Sakamoto, T., Kondo, Y. & Morokuma, K. Generation and suppression of 3-/4-functionalized benzynes using zinc ate base (TMP−Zn−ate): new approaches to multisubstituted benzenes. J. Am. Chem. Soc. 130, 472–480 (2008).
5. Furuyama, T., Yonehara, M., Arimoto, S., Kobayashi, M., Matsumoto, Y. & Uchiyama, M. development of highly chemoselective bulky zincate complex, tBu4ZnLi2: design, structure, and practical applications in small-/macromolecular synthesis. Chem. Eur. J. 14, 10348–10356 (2008).
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