Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Chemical Engineering,General Chemistry
Link
http://www.nature.com/articles/nchem.2861.pdf
Reference44 articles.
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2. Jia, T . et al. A Cu/Pd cooperative catalysis for enantioselective allylboration of alkenes. J. Am. Chem. Soc. 137, 13760–13763 (2015).
3. Lee, Y., Jang, H. & Hoveyda, A. H. Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes. J. Am. Chem. Soc. 131, 18234–18235 (2009).
4. Meng, F., Jang, H. & Hoveyda, A. H. Exceptionally E- and β-Selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: synthesis of enantiomerically enriched vicinal and geminal borosilanes. Chem. Eur. J. 19, 3204–3214 (2013).
5. Nishikawa, D., Hirano, K. & Miura, M. Asymmetric synthesis of α-aminoboronic acid derivatives by copper-catalyzed enantioselective hydroamination. J. Am. Chem. Soc. 137, 15620–15623 (2015).
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