Abstract
AbstractDuring the last years we have witnessed progressive evolution of preparation of acenes with length up to dodecacene by on-surface synthesis in ultra-high vacuum or generation of acenes up to decacene in solid matrices at low temperatures. While these protocols with very specific conditions produce the acenes in amount of few molecules, the strategies leading to the acenes in large quantities dawdle behind. Only recently and after 70 years of synthetic attempts, heptacene has been prepared in bulk phase. However, the preparative scale synthesis of higher homologues still remains a formidable challenge. Here we report the preparation and characterisation of nonacene and show its excellent thermal and in-time stability.
Funder
EraNET Cofund Initiatives QuantERA under the European Union’s Horizon 2020 research and innovation programme grant agreement ORQUID.
MEXT | JST | Exploratory Research for Advanced Technology
JSPS-WPI
EraNET Cofund Initiatives QuantERA under the European Union’s Horizon 2020 research and innovation programme grant agreement ORQUID. CNRS through the MITI interdisciplinary programs
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry,Multidisciplinary
Cited by
20 articles.
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